You have learnt two types of bonds ionic bond and covalent band. But when we try to draw the structure of O3molecule we find these two bonds are not capable to define the bonding involved in O3 molecule.
The coordinate covalent bond is like covalent bond but the only difference is in the way of sharing of electrons. You have seen that in covalent bond both bonded atoms share single electron, this shared pair of electrons makes a bond and both atoms get the equal share of it.
The co-ordinate covalent bond is a kind of partnership where the whole investment is done by one atom while other partner invests nothing but gets the equal share of the company.


If you apply LCAO treatment for O3molecule you will find its bond order is 1.5 which shows that each O-O bond is formed by 1 sigma and half pi bond. The pi bond is delocalised over all three O atoms. So the structure of O3 is best explained by resonating hybrid.
This type of co-ordinate covalent bond is mostly formed by d block elements. We will study about such molecules, when we study “Co-ordination chemistry”.
There is one more type of bond which is called Hydrogen Bond. We will learn about this in our next post.
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